بررسی اثر پراکنش آلاینده هوا (NO2) بر فلزات سنگین موجود در خاک (مطالعه موردی: پالایشگاه میعانات گازی سیراف)

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشجوی کارشناسی ارشد گروه تخصصی ارزیابی و آمایش سرزمین، دانشکده منابع‌طبیعی و محیط‌زیست، دانشگاه علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران

2 استادیار، گروه تخصصی ارزیابی و آمایش سرزمین، دانشکده منابع‌طبیعی و محیط‌زیست، دانشگاه علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران

3 دانشیار، دانشکده محیط‌زیست، پردیس دانشکده های فنی، دانشگاه تهران، ایران

چکیده

در حال حاضر آلودگی هوا در مناطق نفت‌‌خیز و اطراف آن از جمله چالش‌‌های عمده‌‌ای است که متاسفانه منجر به بروز مشکلات مهمی برای کشور و ساکنین منطقه شده است. در مطالعه حاضر برای تعیین همبستگی میان آلاینده NO2 خروجی از فلر پالایشگاه میعانات گازی سیراف و فلزات سنگین خاک، ابتدا نرخ انتشار این آلاینده با استفاده از ضرایب پیشنهادی توسط سازمان حفاظت محیط‌زیست ایالات متحده آمریکا به میزان g/s0417/1 محاسبه شده و در نهایت مدل‌سازی هوا با استفاده از نرم‌افزار AERMOD انجام شد. با توجه به نتایج حاصل از مدل‌سازی بیشترین پراکنش آلاینده‌‌ NO2 بر اساس جهت باد غالب از غرب به شرق است. همچنین نتایج نمونه‌‌برداری خاک در 6 نقطه اطراف سایت با استاندارد سازمان حفاظت محیط‌زیست مقایسه و مشخص شد که در مناطق فوق میزان فلز سرب بالاتر از حد مجاز استاندارد است. با انجام آزمون تحلیل واریانس و آزمون چند دامنه‌‌ای دانکن با نرم‌‌افزار spss، به دلیل پراکنش منابع آلاینده از قبیل فازهای 19، 12، 14، سایت LNG و کارخانه سیمان آرام در غرب سایت، بیشترین پراکنش فلز سرب با توجه به جهت باد غالب (غرب به شرق) به سمت محدوده سایت پالایشگاه میعانات گازی سیراف می‌‌باشد. بررسی همبستگی فلزات سنگین و آلاینده NO2 نشان داد که بین این آلاینده و فلز سرب در خاک به دلیل ایجاد ترکیبات آنیونی نیتریت و نیترات و در نهایت تشکیل نمک، همبستگی مثبت و معنادار است.

کلیدواژه‌ها


عنوان مقاله [English]

Investigating the Role and Influence of Airborne Pollutant (NO2) Dispersion on Heavy Metals in Soil (Case Study of Syraf Gas Condensate Refinery)

نویسندگان [English]

  • Anita Khaleghi 1
  • Maryam Robati 2
  • Abdolreza Karbassi 3
  • Forough Farsad 2
1 M.Sc. Student, Department of Land Assessment and Land Management, Faculty of Natural Resources and Environment, University of Science and Research, Islamic Azad University, Tehran, Iran
2 Assist. Profe. Department of Land Assessment and Planning, Faculty of Natural Resources and Environment, Universityof Science and Research, Islamic Azad University, Tehran, Iran
3 Assoc. Profe. Faculty of Environment, Campus of Technical Faculties, University of Tehran
چکیده [English]

Today, air pollution in oilfield and refinery areas and around it is one of the major challenges that unfortunately creates important problems for the residents of the region.In the present study, to determine the relationship and correlation between NO2 emissions from the flare of Syraf gas condensate refinery and heavy metals in the soil. The emission rate of this pollutant was calculated using the proposed emission factors by the US Environmental Protection Agency 1.0417g/s and the air modeling was done using AERMOD software. The most dispersion of NO2 is based on the wind direction from the west to the east. Sampling results from soil at 6 points around the site were compared with the standards of the Environmental Protection Agency for soil and it was found the lead metal content was higher than the standard. one-way ANOVA and Duncan's multiple domain test used in Spss software, the highest lead dispersion due to the distribution of more pollutant sources such as 19, 12, 14 phases, as well as the LNG site and the Aram Cement Factory located in the western part of the site, is related to this area of the site. The correlation between heavy metals and NO2 pollutants showed that there was a positive and significant correlation between this pollutant and lead metal in soil surface, Because of the Nitrite and Nitrate anionic compounds in the soil, these compounds form salt with the adsorption of lead metal.

کلیدواژه‌ها [English]

  • Siraf refinery
  • Lead metal
  • NO2 pollutant
  • Flare and AERMOD
Abbaspour, M. 2011. Air Pollution Modeling (In Persian)
Addo, M. A.; Darko, E. O.; Gordon, C.; Nyarko, B. J. B. & Gbada go, J. K. 2012. Heavy Metal Concentrations in Road Deposited Dust at Ketu-South District, Ghana. International Journal of Science and Technology, Volume 2 No.1, 28-39.
Ahmed, F. & Ishiga, H. 2006.Tracem et al concentrations in street dusts of Dhaka city , Bangladesh, Atmospheric Environment, 40, 3835–3844
Alonso Hernández, C.; BernalCastillo, J.; BolanosAlvarez, Y.; Gómez Batista, M. & DiazAsencio, M., 2011. Heavy metal content of bottom ashes from fuel oil power plant and oil refinery in Cuba, journal of fuel 90, 2820–2823.
Amato, F.; Pandolfi, M.; Viana, M.; Querol, X.; Alastuey, A. & Moreno, T. 2009. Spatial and chemical patterns of PM10 in road dust deposited in urban environment. Atmospheric Environment, 43, 1650–1659.
Ashrafi, Kh.; Solymani, M.; Momeni, M.; Karami, Sh. & Amoni, A. 2013. Modeling the Emission of Pollutants from Asphalt Plants and Crushers of Road Construction Projects (In Persian)
Atabi, F.; Jafari Gol, F.; Momeni, M.; Soleimiani, M. & Bahmannia,GH. 2014. Modeling the Distribution of CO Pollutants Using AERMOD Software in South Pars 4 Gas Refinery (In Persian)
Bakhtiari, E.; Fize, M. & Bakhtiari, F. 2013. Distribution of Pollutants Released from the Chimney of the Seventh Unit of Tehran Cement on the Surrounding Areas (In Persian)
Bhanarkar, A.; Goyal, S.; Sivacoumar, R. & Chalapati Rao, C. 2005. Assessment of contribution of SO2 and NO2 from different sources in Jamshedpur region, India. Atmos Environ 2005; 39(40): 7745-60.
Bilen, S. 2010. Effect of cement dust Comparison of Total and Bioavailable Heavy Metals in Top Soils of Bonab District in Zanjan Province, Open Journal of Soil Science, 2, 123-132.
Binggan, W. & Linsheng, Y. 2010. A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China, Micro chemical Journal 94, 99–107.
Chen, T. B.; Wong, J. W. C.; Zhou, H. Y. & Wong, M. H. 2014. Assessm ent of trace metal distribution in surface soils of Hong Kong. Environmental Pollution, Vol. 96, No. 1, 61-68
Cimorelli, A. J.; Perry, S. G.; Venkatram, A.; Weil, J. C.; Paine, R. J.; Wilson, R. B.; Lee, R. F.; Peters, W. D.; Brode, R. W. & Paumier, J. O. 2004. AERMOD: description of model formulation”. U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Emissions Monitoring and Analysis Division, Research Triangle Park, North Carolina, EPA-454/R-03-004, 91 pp.
Cimorelli, A. J.; Perry, S. G.; Venkatram, A.; Weil, J. C.; Paine, R. J.; Wilson, R. B.; Lee, R. F.; Peters, W. D. & Brode, R. W. 2005. AERMOD: a dispersion model for industrial source applications. Part I: general model formulation and boundary layer characterization”. Journal of Applied Meteorology 44, 682–693.
Duong, T. & Lee, B. K. 2011. Determining contamination level of heavy metals in road dust from busy traffic areas with different characteristics. Environmental Management.
Environment and Climate Change. 2016. National Pollutant Release Inventory, https://www.ec.gc.ca.
Faiz, Y.; Tufail, M.; Javed, M. T.; Cha udhry, M. M. & Siddique, N. 2009. Road dust pollution of Cd, Cu, Ni, Pb and Zn along Islamabad Expressway, Pakistan. Micro chemical Journal. 92, 186–192
Kanyanee, S.; Vanisa, S.; Kraichat, T. & Anchaleeporn, W. L. 2011. Application of the AERMOD Modeling System for Environmental Impact Assessment of NO2 Emissions from a Cement Complex", Journal of Environmental Sciences, 2011, 23 (6), 931-940.
Khajoui, A.; Zamirian, B. & Permon, Gh. 2015. Basics of the Environment or the Approach to Air Pollution (In Persian)
Li, X.; Liu, L.; Wang, Y.; Luo, G.; Chen, X. & Yang, X. 2015. Heavy metal contamination of urban soil in an old industrial city (Shenyang) in Northeast China. Geoderma. 2015; 192:50-58.
Lu, X.; Wang, L.; Lei, K.; Huan, g.J. & Zhai,Y. 2008. Contamination assessment of copper, lead, zinc, manganese and nickel in street dust of Baoji, NW china, journal of hazardous materials 161, 1058 -1062.
Mazur, M. 2009. Ambient air gaseous mercury concentrations in the vicinity of coalfired power plants in Alberta, Canada”, journal of Science of the Total Environment 408, pp.373-381
Momeni, M. 2012. Statistical Analysis with Spss (In Persian)
Moslempour, M. E. & Shahdadi, S. 2013. Assessment of Heavy Metal Contamination in Soils around of Khash Cement Plant, SE Iran, Earth Sciences, 5: 111-118
Niromand, M.; Moradi, H. & Sufyanian, A. 2014. Investigation of Emission Emissions (CO, NOX, SO2) of Isfahan Petrochemical Using AERMOD VIEW Software (In Persian)
Patel, K. S.; Shukla, A.; Tripathi, A. N. & Hoffman, P. 2001. Heavy metal concentrations of precipitation in east Madhy a Pradesh of India. Water, Air and Soil Pollution, 130, 463-468
Perry, S. G.; Cimorelli, A. J.; Paine, R. J.; Brode, R. W.; Weil, J. C.; Venkatram, A.; Wilson, R. B.; Lee, R. F. & Peters, W. D. 2005. “AERMOD: a dispersion model for industrial source applications. Part II: model performance against 17 field study databases”. Journal of Applied Meteorology 44, 694–708.
Qing, X.; Yutong, Z. & Shenggao, L. 2017. Assessment of heavy metal pollution and human health risk in urban soils of steel industrial city (Anshan), Liaoning, Northeast China. Ecotoxicology and Environmental Safety. 2017; 120:377-85.
Ravankhah, N.; Mirzaei, R. & Masoum, S. 2015. Evaluation of geoaccumulation index, contamination factor, and principal component analysis for estimating soil contamination. Iranian Journal of Health & Environment. 2015; 8(3):345-55
Ritter, C. J. & Rinefierd, S. M. 1983. Natural background and pollution levels of some heavy metals in soils from the area of Dayton, OH. Environmental geology, 5, 73-78
Sezgin, N.; Ozcan, H. K.; Dem ir, G. & Nemlioglu, S. 2003. Dete rumination of heavy metal concentrations in street dusts in Istanbul E-5 highway. Environment International, Vol. 29, No. 7, pp. 979-985.
U.S. Environmental Protection Agency. 2004.”User’s guide for the AMSEPA regulatory model AERMOD”, Office of Air Quality planning and Standards, Emissions Monitoring and Analysis Division, Research Triangle Park North Carolina, EPA-454/B-03-001, 216P.
U.S. Environmental Protection Agency. 2018. “National ambient air quality standards for criteria air pollutant”, htt://www.epa.gov/air/criteria.html.
Zhang, Q. 2008. GIS-based emission inventories of urban scale: A case study of Hangzhou, China, Journal of Atmospheric Environment 42 and 5150–5165. 
Zou, B. 2010. Performance of AERMOD at different time scales”, journal of Simulation Modeling Practice and Theory, 18, pp.612-623